Via Powershell :
(Get-ADDomainController -Filter *).Name | Foreach-Object { repadmin /syncall $_ (Get-ADDomain).DistinguishedName /AdeP }
Via Command Prompt
repadmin /syncall /AdeP
If you now want an immediate sync to Azure Active Directory use this command to force an AAD sync :
Start-ADSyncSyncCycle -PolicyType Delta
Start-ADSyncSyncCycle -PolicyType Initial